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3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(Methyl Orthoacetate) (CAS 16697-49-7)

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Application:
3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(Methyl Orthoacetate) is a synthetic intermediate used in glycosylation reactions
CAS Number:
16697-49-7
Purity:
≥95%
Molecular Weight:
506.59
Molecular Formula:
C30H34O7
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(methyl orthoacetate) is a synthetic intermediate used in glycosylation reactions. Typically, the methyl orthoester protecting group is first removed by mild acid hydrolysis, producing a glycosyl donor. Removal of the O-benzyl protecting groups is performed late in the synthesis.


3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(Methyl Orthoacetate) (CAS 16697-49-7) References

  1. Synthesis of thio-linked disaccharides by 1-->2 intramolecular thioglycosyl migration: oxacarbenium versus episulfonium ion intermediates.  |  Johnston, BD. and Pinto, BM. 2000. J Org Chem. 65: 4607-17. PMID: 10959866
  2. An anionic inositol phosphate glycan pseudotetrasaccharide exhibits high insulin-mimetic activity in rat adipocytes.  |  Chakraborty, N. and d'Alarcao, M. 2005. Bioorg Med Chem. 13: 6732-41. PMID: 16115771
  3. Biotin sulfone as a new tool for synthetic oligosaccharide immobilization: application to multiple analysis profiling and surface plasmonic analysis of anti-Candida albicans antibody reactivity against alpha and beta (1-->2) oligomannosides.  |  Collot, M., et al. 2008. J Med Chem. 51: 6201-10. PMID: 18788729
  4. Synthesis and growth inhibitory properties of glycosides of 1-O-hexadecyl-2-O-methyl-sn-glycerol, analogs of the antitumor ether lipid ET-18-OCH3 (edelfosine).  |  Marino-Albernas, JR., et al. 1996. J Med Chem. 39: 3241-7. PMID: 8765506

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(Methyl Orthoacetate), 1 g

sc-220892
1 g
$238.00