(2-Bromoethoxy)-tert-butyldimethylsilane CAS: 86864-60-0
MF: C8H19BrOS
MW: 239.23
A reagent for N-protection with the TBSO-ethyl group.

(2-Bromoethoxy)-tert-butyldimethylsilane (CAS 86864-60-0)

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Application: (2-Bromoethoxy)-tert-butyldimethylsilane is a reagent for N-protection with the TBSO-ethyl group
CAS Number: 86864-60-0
Molecular Weight: 239.23
Molecular Formula: C8H19BrOS
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data (including water content).

(2-Bromoethoxy)-tert-butyldimethylsilane is a reagent for N-protection with the TBSO-ethyl group. Treatment with Jones reagent effects hydrolysis and concomitant oxidation leading to Nc-acetic acids for further synthetic elaboration. Useful reagent for the Pd-catalyzed N-hydroxyalkylation reactions.


References

1. Hansen, Joshua; et al. Tetrahedron Lett. 47(1), 69-72, (2005) 2. Bressy, Cyril; et al. J. Am. Chem. Soc. 127(38), 13148-13149, (2005) 3. Tetrahedron Lett. 47, 69, (2006)

Physical State :
Liquid
Storage :
Store at 4° C
Boiling Point :
70-75° C (lit.) at 2.5 mmHg
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
Transport :
UN 1903, Packing group II
PubChem CID :
3608067
SMILES :
CC(C)(C)[Si](C)(C)OCCBr

Download SDS (MSDS)

Certificate of Analysis

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