Date published: 2026-4-29

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(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (CAS 37002-48-5)

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Alternate Names:
(+)-DIOP; (4S-trans)-[(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene)]bis(diphenylphosphine); (S,S)-DIOP
CAS Number:
37002-48-5
Molecular Weight:
498.53
Molecular Formula:
C31H32O2P2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Ligand for Rh(I)-catalyzed asymmetric hydrogenation of enamides, 1,4-disilylation of α,-unsaturated ketones,Heck reaction of alkenyl iodides, and hydroformylation of olefins. Useful for the in situ preparation of chiral hydrogenation catalysts.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane, 1 g

sc-254320
1 g
$156.00