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2,3,4,-Tri-O-benzyl-L-fucopyranose (CAS 60431-34-7)

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Alternate Names:
6-Deoxy-2,3,4-tri-O-(phenylmethyl)-L-galactose
Application:
2,3,4,-Tri-O-benzyl-L-fucopyranose is an intermediate used in the preparation of selectin blockers
CAS Number:
60431-34-7
Molecular Weight:
434.52
Molecular Formula:
C27H30O5
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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2,3,4,-Tri-O-benzyl-L-fucopyranose is an intermediate used in the preparation of selectin blockers and other oligosaccharides.


2,3,4,-Tri-O-benzyl-L-fucopyranose (CAS 60431-34-7) References

  1. Preparation and characterization of branched beta-cyclodextrins having alpha-L-fucopyranose and a study of their functions.  |  Nishi, Y. and Tanimoto, T. 2009. Biosci Biotechnol Biochem. 73: 562-9. PMID: 19270374
  2. Oligosaccharides from 'standardized intermediates'. Synthesis of a branched tetrasaccharide glycoside isomeric with the blood-group B, type 2 determinant.  |  Nashed, MA. and Anderson, L. 1983. Carbohydr Res. 114: 43-52. PMID: 6189607
  3. A stereoselective alpha-fucosylation reaction using 1-hydroxy 2,3,4-tri-O-benzyl-L-fucose donor for the practical synthesis of selectin blocker.  |  Kiyoi, T. and Kondo, H. 1998. Bioorg Med Chem Lett. 8: 2845-8. PMID: 9873634
  4. A novel glycosidation promoted by the combination of trimethylsilyl halide and zinc triflate  |  HIGASHI, K., & SUSAKI, H. 1992. Chemical and pharmaceutical bulletin. 40(8): 2019-2022.
  5. 2′-Deoxy-2′-alkoxylaminouridines: Novel 2′-substituted uridines prepared by intramolecular nucleophilic ring opening of 2, 2′-O-anhydrouridines  |  Sebesta, D. P., O'Rourke, S. S., Martinez, R. L., Pieken, W. A., & McGee, D. P. 1996. Tetrahedron. 52(46): 14385-14402.
  6. Glycosyl iodides are highly efficient donors under neutral conditions  |  Hadd, M. J., & Gervay, J. 1999. Carbohydrate research. 320(1-2): 61-69.
  7. An abnormal deallylation reaction of an l-fucopyranoside  |  Li, Z. J., Li, H., Lu, Y. P., Shi, X. L., & Cai, M. S. 1999. Carbohydrate research. 317(1-4): 191-192.
  8. In situ Activating Glycosylation of 6-Deoxysugars: Synthesis of O-. ALPHA.-D-Fucosyl-(1. RAR. 4)-O-. ALPHA.-D-fucosyl-(1. RAR. 4)-O-. ALPHA.-D-quinovosyl-(1. RAR. 4)-D-quinovose  |  Koto, S., Kusunoki, A., & Hirooka, M. 2000. Bulletin of the Chemical Society of Japan. 73(4): 967-976.
  9. Chemical Synthesis of L‐Fucose Derivatives for Acceptor Specificity Characterisation of Plant Cell Wall Glycosyltransferases  |  Damager, I., Olsen, C. E., Egelund, J., Jørgensen, B., Larsen Petersen, B., Ulvskov, P.,.. & Motawia, M. S. 2017. ChemistrySelect. 2(3): 997-1007.
  10. Regioselective Synthesis of Novel Galactose, Fucose and Lactose Fatty Acid Esters as Glycomimetics of Bile Acid 1-O-acyl Galactoside and Bacterial Glycolipids  |  Shehata, S. A., Narouz, M. R., Soliman, S. E., Bassily, R. W., El-Sokkary, R. I., & Nashed, M. A. 2018. Letters in Organic Chemistry. 15(2): 147-154.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

2,3,4,-Tri-O-benzyl-L-fucopyranose, 1 g

sc-220781
1 g
$175.00