Date published: 2026-4-28

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2,2′-Dipyridylamine (CAS 1202-34-2)

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Alternate Names:
bipyam
CAS Number:
1202-34-2
Molecular Weight:
171.20
Molecular Formula:
C10H9N3
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Belonging to the dipyridyl compound family, 2,2′-Dipyridylamine is an organic entity characterized by its colorless, diamagnetic solid state and solubility in employed organic solvents. This versatile compound assumes significance within the realms of electrochemistry and catalysis, playing a pivotal role in unraveling the intricacies of organic molecule structure and reactivity. In coordination chemistry, 2,2′-Dipyridylamine emerges as a noteworthy ligand, engendering complexes with transition metals like iron, cobalt, and nickel. These intricate complexes find application as catalysts in diverse reactions, encompassing hydrogenation and hydroformylation. Beyond catalysis, these complexes contribute to the synthesis of assorted organic entities, including pharmaceuticals and other compounds, thus exemplifying the compound′s broad-reaching influence.


2,2′-Dipyridylamine (CAS 1202-34-2) References

  1. Unusual monodentate binding mode of 2,2'-dipyridylamine (L) in isomeric trans-(acac)2RuII(L)2, trans-[(acac)2RuIII(L)2]ClO4, and cis-(acac)2RuII(L)2 (acac = acetylacetonate). synthesis, structures, and spectroscopic, electrochemical, and magnetic aspects.  |  Kar, S., et al. 2005. Inorg Chem. 44: 1571-9. PMID: 15733000
  2. Synthesis, structure and biological activity of copper(II) complexes with oxolinic acid.  |  Psomas, G., et al. 2006. J Inorg Biochem. 100: 1764-73. PMID: 16904184
  3. Copper(II) complexes with sparfloxacin and nitrogen-donor heterocyclic ligands: Structure-activity relationship.  |  Efthimiadou, EK., et al. 2008. J Inorg Biochem. 102: 910-20. PMID: 18242712
  4. A macrophage cell model for selective metalloproteinase inhibitor design.  |  Jacobsen, FE., et al. 2008. Chembiochem. 9: 2087-95. PMID: 18666306
  5. Diversity of azido magnetic chains constructed with flexible ligand 2,2'-dipyridylamine.  |  Wang, XT., et al. 2009. Inorg Chem. 48: 1301-8. PMID: 19146431
  6. Coordination polymers of zinc with (η6-benzenecarboxylate) chromium tricarbonyl.  |  Murugesapandian, B. and Roesky, PW. 2011. Inorg Chem. 50: 1698-704. PMID: 21189026
  7. Selective, sensitive and reversible 'turn-on' fluorescent cyanide probes based on 2,2'-dipyridylaminoanthracene-Cu2+ ensembles.  |  Xie, Y., et al. 2012. Chem Commun (Camb). 48: 11513-5. PMID: 23090603
  8. Zinc complexes of salicylaldehydes: synthesis, characterization and DNA-binding properties.  |  Zianna, A., et al. 2013. J Inorg Biochem. 127: 116-26. PMID: 23973683
  9. Electrocatalysis of molecular oxygen reduction reaction at liquid-liquid interface and DFT computational study of proton transfer from the conjugate acid of 2,2'-dipyridylamineto oxygen.  |  Soleymani-Bonoti, F. 2020. J Mol Model. 26: 350. PMID: 33236209
  10. Ultrafine Pt-Ni nanoparticles in hollow porous carbon spheres for remarkable oxygen reduction reaction catalysis.  |  Wan, XK., et al. 2021. Dalton Trans. 50: 6811-6822. PMID: 33890597
  11. A highly sensitive chemosensor for rapid recognition of Cu2+ and HSO3- in 100% aqueous solution.  |  Ou, Z., et al. 2021. Spectrochim Acta A Mol Biomol Spectrosc. 263: 120215. PMID: 34325174
  12. Deciphering Spectroscopic and Structural Insights into the Photophysical Behavior of 2,2'-Dipyridylamine: An Efficient Environment Sensitive Fluorescence Probe.  |  Rohman, MA., et al. 2021. J Phys Chem A. 125: 6964-6975. PMID: 34372657
  13. trans-Bis(2,2'-di-pyridyl-amine-κ2 N,N')-bis-(1,1,3,3-tetra-cyano-2-eth-oxy-propenido-κN)copper(II).  |  Saadallah, Y., et al. 2022. IUCrdata. 7: x221180. PMID: 36628191
  14. Steric hindrance, ligand ejection and associated photocytotoxic properties of ruthenium(II) polypyridyl complexes.  |  Herrera-Ramírez, P., et al. 2023. J Biol Inorg Chem. 28: 403-420. PMID: 37059909
  15. Synthesis, characterization, cytotoxic, and DNA binding studies of some platinum (II) complexes of 1,2-diamine and alpha-diimine with 2-pyridinecarboxylate anion.  |  Paul, AK., et al. 1996. J Inorg Biochem. 61: 179-96. PMID: 9064362

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

2,2′-Dipyridylamine, 5 g

sc-251821
5 g
$97.00