Date published: 2026-6-4

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2,2′-Bipyridinium chlorochromate (CAS 76899-34-8)

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CAS Number:
76899-34-8
Molecular Weight:
292.64
Molecular Formula:
C10H9ClCrN2O3
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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2,2′-Bipyridinium chlorochromate (BPC) is an organic compound that serves as a versatile and powerful oxidizing agent, particularly utilized in the field of organic chemistry for the selective oxidation of a wide range of organic substrates. Its mechanism of action involves the transfer of an oxygen atom from the chlorochromate moiety to the substrate, enabling the efficient conversion of primary alcohols to aldehydes, secondary alcohols to ketones, and the oxidation of other sensitive functional groups under mild conditions. This specificity and mildness make 2,2′-Bipyridinium chlorochromate an indispensable tool in synthetic organic chemistry, especially in complex molecule synthesis where selective oxidation can be challenging. Moreover, the 2,2′-bipyridinium core of 2,2′-Bipyridinium chlorochromate facilitates electron transfer processes, enhancing its oxidative capabilities while maintaining control over the reaction conditions. This property is particularly beneficial in the synthesis of fine chemicals and in the development of new materials, where precision and selectivity are paramount. The use of 2,2′-Bipyridinium chlorochromate in research has also opened avenues for the exploration of novel organic transformations, contributing to the advancement of synthetic methodologies and the discovery of new reaction pathways.


2,2′-Bipyridinium chlorochromate (CAS 76899-34-8) References

  1. m-Chloroperbenzoic acid-oxchromium (VI)-mediated cleavage of 2,4,5-trisubstituted oxazoles.  |  Patil, PC. and Luzzio, FA. 2017. Tetrahedron Lett. 58: 1280-1282. PMID: 28970642
  2. Kinetics and mechanism of the oxidation of some α-hydroxy acids by 2,2′-bipyridinium chlorochromate  |  Vinita Kumbhat, Pradeep K. Sharma, Kalyan K. Banerji. 2002. International Journal of Chemical Kinetics. 34: 248-254.
  3. Kinetics and mechanism of the oxidation of organic sulphides by 2,2′-bipyridinium chlorochromate  |  Shashi Vyas & Pradeep K. Sharma. 2002. Journal of Chemical Sciences volume. 114: 137–148.
  4. Efficient and Convenient Deprotection of Thiocarbonyl to Carbonyl Compounds Using 3-Carboxypyridinium and 2,2′-Bipyridinium Chlorochromates in Solution, Dry Media, and under Microwave Irradiation  |  Iraj Mohammadpoor-Baltork, Hamid Reza Memarian & Kiumars Bahrami. 2004. Monatshefte für Chemie / Chemical Monthly. 135: 411–418.
  5. A direct arylation-oxidation route to 3-arylisoindolinone inhibitors of MDM2-p53 interaction  |  Richard K. Dempster, Frederick A. Luzzio. 2011. Tetrahedron Letters. 52: 4992-4995.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

2,2′-Bipyridinium chlorochromate, 25 g

sc-230764
25 g
$97.00

2,2′-Bipyridinium chlorochromate, 100 g

sc-230764A
100 g
$383.00