Date published: 2025-12-5

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[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (CAS 79255-71-3)

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Alternate Names:
[Rh(dppb)(COD)]BF4
CAS Number:
79255-71-3
Molecular Weight:
724.36
Molecular Formula:
C36H40BF4P2Rh
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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1,4-Bis(diphenylphosphino)butanerhodium(I) tetrafluoroborate is a rhodium complex used primarily as a catalyst in organic synthesis. The presence of 1,4-bis(diphenylphosphino)butane (dppb) as a bidentate ligand allows for the stabilization of the rhodium center, promoting its reactivity in catalytic cycles. This complex is particularly relevant in homogeneous catalysis where it facilitates a variety of reactions, including hydrogenation, hydroformylation, and carbon-carbon bond formation. The 1,5-cyclooctadiene (cod) ligand also plays a role in modulating the reactivity and solubility of the complex. Research involving this compound often explores its application in asymmetric synthesis, where the chirality of the ligands surrounding the rhodium center can induce enantioselectivity in the products. The counterion, tetrafluoroborate, contributes to the overall stability and solubility of the complex in various solvents, making it a versatile reagent for exploring reaction mechanisms and kinetics in solution.


[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (CAS 79255-71-3) References

  1. Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines.  |  Takemiya, A. and Hartwig, JF. 2006. J Am Chem Soc. 128: 6042-3. PMID: 16669666

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 100 mg

sc-229827
100 mg
$110.00

[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 500 mg

sc-229827A
500 mg
$364.00