Molecular structure of 1,4,7-Trimethyl-1,4,7-triazacyclononane, CAS Number: 96556-05-7
1,4,7-Trimethyl-1,4,7-triazacyclononane (CAS 96556-05-7)
CAS Number:
96556-05-7
Molecular Weight:
171.28
Molecular Formula:
C9H21N3
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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1,4,7-Trimethyl-1,4,7-triazacyclononane is a complexing agent that forms stable complexes with metal ions, particularly transition metals such as copper, nickel, and cobalt. It functions as a chelating agent, binding to metal ions through its nitrogen atoms to form stable coordination complexes. 1,4,7-Trimethyl-1,4,7-Triazacyclononane′s mechanism of action involves the formation of these stable complexes, which can be utilized in various experimental applications such as catalysis, metal extraction, and metal ion sensing. In a research and development setting, 1,4,7-Trimethyl-1,4,7-triazacyclononane can be used to study the behavior of metal ions in solution, as well as to design and synthesize new metal-based materials. Its ability to form stable complexes with metal ions may be a useful for investigating the reactivity and coordination chemistry of metal ions in various experimental systems.
1,4,7-Trimethyl-1,4,7-triazacyclononane (CAS 96556-05-7) References
- Tmtacn, tacn, and triammine complexes of (eta 6-arene)OsII: syntheses, characterizations, and photosubstitution reactions (tmtacn = 1,4,7-trimethyl-1,4,7-triazacyclononane; tacn = 1,4,7-triazacyclononane). | Wang, R., et al. 2001. Inorg Chem. 40: 593-600. PMID: 11225098
- Osmium Complexes of 1,4,7-Triazacyclononane (tacn) and 1,4,7-Trimethyl-1,4,7-triazacyclononane (Me(3)tacn) and the X-ray Crystal Structure of [(Me(3)tacn)Os(eta(6)-C(6)H(5)BPh(3))]BPh(4).CH(3)CN. | Ware, DC., et al. 1996. Inorg Chem. 35: 2576-2582. PMID: 11666472
- Exchange Coupling in an Isostructural Series of Face-Sharing Bioctahedral Complexes [LM(II)(&mgr;-X)(3)M(II)L]BPh(4) (M = Mn, Fe, Co, Ni, Zn; X = Cl, Br; L = 1,4,7-Trimethyl-1,4,7-triazacyclononane). | Bossek, U., et al. 1997. Inorg Chem. 36: 2834-2843. PMID: 11669919
- Oxidatively Induced Reductive Eliminations. A Mechanistic Study of the Oxidation Chemistry of CnRhMe(3) (Cn = 1,4,7-Trimethyl-1,4,7-triazacyclononane). | Fooladi, E. and Tilset, M. 1997. Inorg Chem. 36: 6021-6027. PMID: 11670234
- A silica gel-supported ruthenium complex of 1,4,7-trimethyl-1,4,7-triazacyclononane as recyclable catalyst for chemoselective oxidation of alcohols and alkenes by tert-butyl hydroperoxide. | Cheung, WH., et al. 2002. J Org Chem. 67: 7716-23. PMID: 12398494
- Formation and reaction of O=MnV species in the oxidation of phenolic substrates with H2O2 catalysed by the dinuclear manganese(IV) 1,4,7-trimethyl-1,4,7-triazacyclononane complex [MnIV2(mu-O)3(TMTACN)2](PF6)2. | Gilbert, BC., et al. 2004. Org Biomol Chem. 2: 1176-80. PMID: 15064795
- Reactions of (di)manganese carbonyl ions with 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3TACN) in the gas phase. | van Beelen, ES. and Ingemann, S. 2005. Rapid Commun Mass Spectrom. 19: 317-22. PMID: 15660451
- Alkene cis-dihydroxylation by [(Me3tacn)(CF3CO2)RuVI O2)]ClO4(Me(3)tacn = 1,4,7-Trimethyl-1,4,7-triazacyclononane): structural characterization of [3 + 2] cycloadducts and kinetic studies. | Yip, WP., et al. 2005. J Am Chem Soc. 127: 14239-49. PMID: 16218618
- Spectroscopic investigation of the charge-transfer interactions between 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil. | AlQaradawi, SY. and Nour, EM. 2007. Spectrochim Acta A Mol Biomol Spectrosc. 68: 908-11. PMID: 17307029
- Synthesis, spectroscopic and thermal investigations of solid charge-transfer complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil. | Alqaradawi, SY., et al. 2008. Spectrochim Acta A Mol Biomol Spectrosc. 71: 1594-8. PMID: 18691934
- Aluminum-stabilized low-spin iron(II) hydrido complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane. | Oishi, M., et al. 2014. Inorg Chem. 53: 5100-8. PMID: 24801527
- The Zn(II)-1,4,7-Trimethyl-1,4,7-Triazacyclononane Complex: A Monometallic Catalyst Active in Two Protonation States. | Diez-Castellnou, M., et al. 2019. Front Chem. 7: 469. PMID: 31334218
- (1,4,7-trimethyl-1,4,7-triazacyclononane)iron (III)-mediated cleavage of DNA: detection of selected protein-DNA interactions. | Ehmann, A., et al. 1998. Nucleic Acids Res. 26: 2086-91. PMID: 9547264
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
1,4,7-Trimethyl-1,4,7-triazacyclononane, 100 mg | sc-253994 | 100 mg | $62.00 |