Date published: 2026-5-17

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1,3-Bis(di-tert-butylphosphinomethyl)benzene (CAS 149968-36-5)

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Alternate Names:
PCP pincer
CAS Number:
149968-36-5
Purity:
97%
Molecular Weight:
394.55
Molecular Formula:
C24H44P2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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1,3-Bis(di-tert-butylphosphinomethyl)benzene is a chelating ligand used in coordination chemistry and organometallic research to synthesize transition metal complexes with unique properties. The steric bulk provided by the di-tert-butyl groups influences the coordination environment of the metal center, which is for studying catalytic processes and reaction mechanisms. As such, 1,3-Bis(di-tert-butylphosphinomethyl)benzene is often employed in the design of catalysts for homogeneous catalysis, including hydrogenation reactions, carbon-carbon bond formation, and small molecule activation. In addition, this compound is used in the creation of materials with magnetic and electronic properties for potential use in molecular electronics and spintronics. The ability of 1,3-Bis(di-tert-butylphosphinomethyl)benzene to stabilize unusual oxidation states of metals also makes it useful in exploring the fundamentals of metal-ligand interactions and expanding the knowledge of coordination chemistry.


1,3-Bis(di-tert-butylphosphinomethyl)benzene (CAS 149968-36-5) References

  1. Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands.  |  Prechtl, MH., et al. 2007. Chemistry. 13: 1539-46. PMID: 17117397
  2. Cationic, neutral, and anionic PNP Pd(II) and Pt(II) complexes: dearomatization by deprotonation and double-deprotonation of pincer systems.  |  Feller, M., et al. 2010. Inorg Chem. 49: 1615-25. PMID: 20067235

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

1,3-Bis(di-tert-butylphosphinomethyl)benzene, 250 mg

sc-222923
250 mg
$66.00

1,3-Bis(di-tert-butylphosphinomethyl)benzene, 1 g

sc-222923A
1 g
$189.00