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1,1′-Carbonylbis(3-methylimidazolium) Triflate (CAS 120418-31-7)

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Alternate Names:
1,1′-Carbonylbis[3-methyl-1H-imidazolium; 1,1,1-Trifluoromethanesulfonate;
Application:
1,1′-Carbonylbis(3-methylimidazolium) Triflate is an efficient reagent for aminoacylations
CAS Number:
120418-31-7
Molecular Weight:
490.36
Molecular Formula:
C9H12N4O•2F3CSO3
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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1,1′-Carbonylbis(3-methylimidazolium) Triflate is a chemical compound that functions as a phase-transfer catalyst in various organic synthesis reactions. Its mechanism of action involves facilitating the transfer of a reactant from one phase to another, typically from an aqueous phase to an organic phase, by forming a complex with the reactant and transporting it across the phase boundary. 1,1′-Carbonylbis(3-Methylimidazolium) Triflate acts by increasing the solubility of the reactant in the organic phase, thereby accelerating the reaction rate and improving the overall yield of the desired product. In this capacity, 1,1′-Carbonylbis(3-methylimidazolium) Triflate may play a role in promoting efficient and selective chemical transformations in research and development applications. Its ability to facilitate phase-transfer reactions may be a useful for synthetic chemists seeking to optimize reaction conditions and improve the efficiency of various organic synthesis processes.


1,1′-Carbonylbis(3-methylimidazolium) Triflate (CAS 120418-31-7) References

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  2. Fluorinated 9H-xanthene-9-carboxylic acid oxazol-2-yl-amides as potent, orally available mGlu1 receptor enhancers.  |  Vieira, E., et al. 2009. Bioorg Med Chem Lett. 19: 1666-9. PMID: 19233648
  3. Bicyclic Caged Morpholino Oligonucleotides for Optical Gene Silencing.  |  Pattanayak, S., et al. 2022. Chembiochem. 23: e202200374. PMID: 36068175
  4. 1,1'-Carbonylbis(3-methylimidazolium) triflate: an efficient reagent for aminoacylations  |  Ashis K. Saha, Henry Rapoport, and Peter Schultz. 1989. J. Am. Chem. Soc., 111, 13,: 4856–4859.
  5. Enantiomerically pure dimethyl (2S)-N-(9-phenylfluoren-9-yl)-3,4-didehydroglutamate as chiral educt. Chirospecific synthesis of (+)-5-O-carbamoylpolyoxamic acid and 3-alkylglutamates  |  Manuel M. Paz and F. Javier Sardina. 1993,. J. Org. Chem. 58, 25,: 6990–6995.
  6. Carboxy Terminus Coupling Using 1,1'-Carbonylbis(3-methylimidazolium triflate) (CBMIT) in the Presence of Cu(II) Salts  |  Frank S. Gibson and Henry Rapoport. 1995,. J. Org. Chem. 60, 8,: 2615–2617.
  7. Synthesis of peptidosialosides and peptidosaccharides  |  S Sabesan - Tetrahedron letters, 1997 - Elsevier. 5 May 1997,. Tetrahedron Letters. Pages 3127-3130: Volume 38, Issue 18,.
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  9. Toward waste-free peptide synthesis using ionic reagents and ionic liquids as solvents  |  N Galy, MR Mazières, JC Plaquevent - Tetrahedron Letters, 2013 - Elsevier. 22 May 2013,. Tetrahedron Letters. Pages 2703-2705: Volume 54, Issue 21,.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

1,1′-Carbonylbis(3-methylimidazolium) Triflate, 1 g

sc-208711
1 g
$306.00