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1,1,2,2-Tetrachloroethane (CAS 79-34-5)

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Alternate Names:
Acetylene tetrachloride
CAS Number:
79-34-5
Purity:
≥98%
Molecular Weight:
167.85
Molecular Formula:
C2H2Cl4
Supplemental Information:
This is as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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1,1,2,2-Tetrachloroethane is a chlorinated hydrocarbon with the chemical formula C2H2Cl4, characterized by the presence of four chlorine atoms symmetrically substituted on a two-carbon ethane backbone. This structure imparts high density, low flammability, and chemical stability, making it useful in various industrial and research applications. Historically, 1,1,2,2-Tetrachloroethane has been utilized as a solvent in the manufacturing of other chemicals, as well as in cleaning and degreasing operations. In scientific research, this chemical has been particularly valuable as a non-polar solvent in organic synthesis, facilitating reactions that are sensitive to the polar nature of more common solvents like water or methanol. Its ability to dissolve a wide range of organic compounds without participating in reactions makes it an ideal medium for carrying out complex chemical syntheses. Additionally, the high electron density of the chlorine atoms in 1,1,2,2-Tetrachloroethane makes it an interesting subject in studies of reaction mechanisms involving halogen participation. Researchers have utilized it to study halogen bonding interactions and the stabilization of ionic intermediates in substitution and elimination reactions. Its role in environmental science has also been significant, particularly in studies related to the degradation and persistence of chlorinated hydrocarbons in ecosystems, helping scientists understand and mitigate the environmental impacts of halogenated organic compounds.


1,1,2,2-Tetrachloroethane (CAS 79-34-5) References

  1. Degradation of 1,1,2,2-tetrachloroethane and accumulation of vinyl chloride in wetland sediment microcosms and in situ porewater: biogeochemical controls and associations with microbial communities.  |  Lorah, MM. and Voytek, MA. 2004. J Contam Hydrol. 70: 117-45. PMID: 15068871
  2. Anaerobic bioremediation of groundwater containing a mixture of 1,1,2,2-tetrachloroethane and chloroethenes.  |  Aulenta, F., et al. 2006. Biodegradation. 17: 193-206. PMID: 16715399
  3. 1,1,2,2-tetrachloroethane reactions with OH-, Cr(II), granular iron, and a copper-iron bimetal: insights from product formation and associated carbon isotope fractionation.  |  Elsner, M., et al. 2007. Environ Sci Technol. 41: 4111-7. PMID: 17612198
  4. Biodegradation of 1,1,2,2-tetrachloroethane in Upflow anaerobic sludge blanket (UASB) reactor.  |  Basu, D. and Gupta, SK. 2010. Bioresour Technol. 101: 21-5. PMID: 19699084
  5. Discovery of a trans-dichloroethene-respiring Dehalogenimonas species in the 1,1,2,2-tetrachloroethane-dechlorinating WBC-2 consortium.  |  Manchester, MJ., et al. 2012. Appl Environ Microbiol. 78: 5280-7. PMID: 22635995
  6. Enhanced dehydrochlorination of 1,1,2,2-tetrachloroethane by graphene-based nanomaterials.  |  Li, X., et al. 2016. Environ Pollut. 214: 341-348. PMID: 27107258
  7. Dehydrochlorination of adsorbed 1,1,2,2-tetrachloroethane on graphene oxide-based materials' surface: Comparison with dissolved form in aqueous environment.  |  Chen, W. and Ni, J. 2017. J Hazard Mater. 324: 321-328. PMID: 27816377
  8. Anti-passivation ability of sulfidated microscale zero valent iron and its application for 1,1,2,2-tetrachloroethane degradation.  |  Fan, B., et al. 2023. J Hazard Mater. 443: 130194. PMID: 36270192
  9. Solute-solvent interactions. IV. Infrared studies of solvent effects on rotational isomers of 1, 2-dichloroethane and 1, 1, 2, 2-tetrachloroethane  |  Oi, N., & Coetzee, J. F. 1969. Journal of the American Chemical Society. 91(10): 2478-2481.
  10. 1, 1, 2, 2‐Tetrachloroethane (TeCA) as a Solvent Additive for Organic Hole Transport Materials and Its Application in Highly Efficient Solid‐State Dye‐Sensitized Solar Cells  |  Xu, B., Gabrielsson, E., Safdari, M., Cheng, M., Hua, Y., Tian, H.,.. & Sun, L. 2015. Advanced Energy Materials. 5(10): 1402340.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

1,1,2,2-Tetrachloroethane, 25 g

sc-356264
25 g
$40.00

1,1,2,2-Tetrachloroethane, 100 g

sc-356264A
100 g
$50.00