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Nitrosyl hexafluorophosphate (CAS 16921-91-8)

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Alternate Names:
Nitrosonium hexafluorophosphate
CAS Number:
16921-91-8
Molecular Weight:
174.97
Molecular Formula:
F6NOP
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Nitrosonium hexafluorophosphate, or NMDS-PF6, is a significant reagent employed in organic synthesis, biochemistry, and scientific research. It serves as a catalyst to facilitate the production of diverse organic compounds and as a reagent to investigate the biochemical and physiological impacts of specific substances. It aids in exploring the biochemical and physiological effects of specific substances.


Nitrosyl hexafluorophosphate (CAS 16921-91-8) References

  1. Polymerization of epoxides and vinyl monomers by nitrosyl hexafluorophosphate  |  , et al. (1985). Polymer Bulletin. volume 13,: pages 337–342.
  2. Complexes of trivalent phosphorus derivatives. XI. Reactions of cyclopentadienylmanganese dicarbonyl nitrosyl hexafluorophosphate with various tertiary phosphines and related ligands  |  Robert Bruce King and A. Efraty. 1969,. Inorg. Chem. 8, 11,: 2374–2379.
  3. Reactions of metal carbonyl derivatives. Part XV. Oxidation studies of some η-cyclopentadienyl bridging sulphido- and phosphino-derivatives of iron  |  Jacob A. de Beer, Raymond J. Haines, Robert Greatrex and Jan A. van Wyk. 1973,. J. Chem. Soc., Dalton Trans.,. Issue 21, 1973: 2341-2346.
  4. Stereochemistry of sulfur compounds. V. Stereochemical reaction cycles that involve cyclic sulfoxides, sulfimides, and sulfoximides  |  Frederick G. Yamagishi, Dennis R. Rayner, Evelyn T. Zwicker, and Donald J. Cram. 1973. J. Am. Chem. Soc., 95, 6,: 1916–1925.
  5. Metal nitrosyl complexes. I. Cyclobutadieneiron nitrosyl derivatives  |  Avi. Efraty, R. Bystrek, J. A. Geaman, S. S. Sandhu, M. H. A. Huang, and R. H. Herber. 1974. Inorg. Chem., 13, 6,: 1269–1272.
  6. Studies of heterocyclic compounds. Part XVI. Mechanism of electrophilic substitution of 6a-thiathiophthens and related compounds: nitrosation with rearrangement  |  Robert M. Christie, Alexander S. Ingram, David H. Reid and Robert G. Webster. 1974,. J. Chem. Soc., Perkin Trans. 1,: 722-728.
  7. Electrochemical oxidation and protonation of octahydrotriborate anion  |  Patrick J. Dolan, John H. Kindsvater, and Dennis G. Peters. 1976. Inorg. Chem., 15, 9,: 2170–2173.
  8. Preparation and Properties of Nitrosyl Complexes of Molybdenum  |  Tatsumi Takashi 1, Sekizawa Kazuhiko 1, Tominaga Hiroo 1. 1980,. Bulletin of the Chemical Society of Japan. Vol.53, No.8: 2297-2303.
  9. Vibrational spectra of cyclic dithioethers and their dications. 2. Raman spectra and conformations of the monocation radicals and dications of 1,5-dithiacyclooctane and related dithioethers  |  Makiko Tamaoki, Masanori Serita, Yasushi Shiratori, and Koichi Itoh. 1989,. J. Phys. Chem. 93, 16,: 6052–6058.
  10. Solution processing of a doped conducting polymer  |  GW Heffner, DS Pearson - Synthetic metals, 1991 - Elsevier. September 1991,. Synthetic Metals. Volume 44, Issue 3,: Pages 341-347.
  11. Preparation and reactivity of dichalcogenide (S, Se) dication salts from medium-sized cyclic bis-sulfide and bis-selenides  |  H Fujihara, R Akaishi, N Furukawa - Tetrahedron, 1993 - Elsevier. 1993,. Tetrahedron. Volume 49, Issue 8,: Pages 1605-1618.
  12. Acetal-Functionalized Indacenodithiophene (IDT): Controlling the Position of a Lewis Acidic Dopant for Improved Thermoelectricity  |  Jinhwan Byeon, Dowon Kim, Minkyu Kyeong, In Gyu Bak, and Sukwon Hong*. 2023,. Chem. Mater. 35, 5,: 2133–2145.
  13. Nucleophilic addition to coordinated allyl ligands. Heteroatom nucleophiles with cationic molybdenum complexes  |  WE Vanarsdale, REK Winter, JK Kochi - Journal of organometallic …, 1985 - Elsevier. 26 November 1985,. Journal of Organometallic Chemistry. Volume 296, Issues 1–2,: Pages 31-54.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Nitrosyl hexafluorophosphate, 25 g

sc-257922
25 g
$357.00