Date published: 2025-11-20

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Butyl 3-mercaptopropionate (CAS 16215-21-7)

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Alternate Names:
butyl 3-sulfanylpropanoate
Application:
Butyl 3-mercaptopropionate is a cross-linker and self-assembling monolayer reagent
CAS Number:
16215-21-7
Molecular Weight:
162.25
Molecular Formula:
C7H14O2S
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Butyl 3-mercaptopropionate is a chemical compound characterized by its mercapto (thiol) group attached to a propionate chain, which is further esterified with a butyl group. This structure confers unique properties making it an invaluable agent in various industrial and research applications, particularly in polymer chemistry and materials science. The mercapto group (-SH) at its core is highly reactive, primarily engaging in thiol-ene reactions that are crucial for creating crosslinks within polymers. This reactivity allows butyl 3-mercaptopropionate to act as a chain transfer agent in radical polymerizations, effectively controlling the molecular weight and structure of the resulting polymers. Its role in polymer modification is significant, as it introduces functional groups that can enhance the physical properties of polymers, such as flexibility, adhesion, and chemical resistance, which are essential for coatings, adhesives, and sealants. Additionally, the ester group contributes to the solubility and processability of the compound, facilitating its incorporation into various formulations. In research settings, butyl 3-mercaptopropionate has been utilized to study the kinetics and mechanisms of polymerization reactions and to develop new materials with tailored properties through precise control of polymer architecture and functionality. This compound′s ability to modify material properties while maintaining stability and reactivity under diverse conditions underscores its versatility and importance in advancing material science innovations.


Butyl 3-mercaptopropionate (CAS 16215-21-7) References

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  3. A general approach to the synthesis of 5-S-functionalized pyrimidine nucleosides and their analogues.  |  Kananovich, DG., et al. 2014. Org Biomol Chem. 12: 5634-44. PMID: 24962358
  4. Determining Michael Acceptor Reactivity from Kinetic, Mechanistic, and Computational Analysis for the Base-catalyzed Thiol-Michael Reaction.  |  Huang, S., et al. 2021. Polym Chem. 12: 3619-3628. PMID: 34484433
  5. High-Glass-Transition Polyesters Produced with Phthalic Anhydride and Epoxides by Ring-Opening Copolymerization (ROCOP).  |  Silvano, S., et al. 2023. Polymers (Basel). 15: PMID: 37447447
  6. Effects of Monomer Functionality and Hydrogen Bonding on the Polymerization Kinetics and Properties of Thiol− Ene Networks.  |  Zhou, Hui, et al. 2009. Macromolecules. 42.8: 2994-2999.
  7. Reaction rates and mechanisms for radical, photoinitated addition of thiols to alkynes, and implications for thiol− Yne photopolymerizations and click reactions.  |  Fairbanks, Benjamin D., et al. 2010. Macromolecules. 43.9: 4113-4119.
  8. Thermolysis of LDPE with mercaptoesters: a comparative thermal study.  |  Parthasarathy, V., et al. 2013. J Chem Sci Tech. 2.4: 197-208.
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Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Butyl 3-mercaptopropionate, 100 ml

sc-396842
100 ml
$37.00