Molecular structure of (S)-BINAPINE, CAS Number: 528854-26-4
(S)-BINAPINE (CAS 528854-26-4)
CAS Number:
528854-26-4
Molecular Weight:
734.89
Molecular Formula:
C52H48P2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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Demonstates excellent reactivity and enantioselectivity for the asymmetric hydrogenation of Z-β-aryl(β-acylamino)acrylates.(S)-Binapine is a member of the 2-amino-1,2-diphenylethane family and possesses chirality. It finds extensive applications in organic chemistry, particularly as a chiral ligand in asymmetric synthesis reactions. Additionally, it has proven to be a catalyst in various reactions.
(S)-BINAPINE (CAS 528854-26-4) References
- Nickel-Catalyzed Enantioselective Hydrogenation of β-(Acylamino)acrylates: Synthesis of Chiral β-Amino Acid Derivatives. | Li, X., et al. 2017. Org Lett. 19: 5130-5133. PMID: 28892636
- Nickel-Catalyzed N-Alkylation of Acylhydrazines and Arylamines Using Alcohols and Enantioselective Examples. | Yang, P., et al. 2017. Angew Chem Int Ed Engl. 56: 14702-14706. PMID: 28960690
- Nickel-catalyzed asymmetric hydrogenation of β-acylamino nitroolefins: an efficient approach to chiral amines. | Gao, W., et al. 2017. Chem Sci. 8: 6419-false. PMID: 29163927
- Rhodium-Catalyzed Highly Regio- and Enantioselective Hydrogenation of Tetrasubstituted Allenyl Sulfones: An Efficient Access to Chiral Allylic Sulfones. | Long, J., et al. 2018. Angew Chem Int Ed Engl. 57: 13248-13251. PMID: 30125445
- Nickel-Catalyzed Highly Enantioselective Hydrogenation of β-Acetylamino Vinylsulfones: Access to Chiral β-Amido Sulfones. | Long, J., et al. 2018. Org Lett. 20: 5914-5917. PMID: 30207480
- A cheap metal for a challenging task: nickel-catalyzed highly diastereo- and enantioselective hydrogenation of tetrasubstituted fluorinated enamides. | Guan, YQ., et al. 2019. Chem Sci. 10: 252-256. PMID: 30746080
- Rhodium-Catalyzed Asymmetric Hydrogenation of Tetrasubstituted Cyclic Enamides: Efficient Access to Chiral Cycloalkylamine Derivatives | Xiuxiu Li, Cai You, Hailong Yang, Jinteng Che, Pengyu Chen, Yusheng Yang, Hui Lv, Xumu Zhang. 2017. 359: 597-602.
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| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
(S)-BINAPINE, 50 mg | sc-258133 | 50 mg | $260.00 |