Date published: 2025-9-5

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Rhodium(II) heptafluorobutyrate dimer (CAS 73755-28-9)

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Alternate Names:
DIRHODIUM(II) TETRAKIS(PERFLUOROBUTYRATE)
Application:
Rhodium(II) heptafluorobutyrate dimer is a chemical used in the catalytic preparation of macrocycles and in the efficient synthesis of chiral β-substituted (E)-crotylsilanes
CAS Number:
73755-28-9
Molecular Weight:
1057.93
Molecular Formula:
C16F28O8Rh2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Rhodium(II) heptafluorobutyrate dimer, also known as Rh-Rh, is a coordination complex of rhodium that finds extensive use in scientific research. This complex consists of two rhodium atoms connected by a single bond and possesses a total of eight ligands, these ligands consist of a central carbon atom bonded to seven fluorine atoms. The Rhodium(II) heptafluorobutyrate dimer complex has demonstrated its versatility across various scientific research fields, including catalysis, electrochemistry, and materials science. It serves as a catalyst in the synthesis of organic compounds and facilitates the electrochemical reduction of organic compounds. Moreover, it exhibits remarkable efficiency as a catalyst for the reduction of carbon dioxide, a significant achievement in materials science. Additionally, this complex has contributed to the understanding of the structure and reactivity of transition metal complexes. While the precise mechanism of action of Rhodium(II) heptafluorobutyrate dimer, is not yet fully comprehended, it is believed to function as a Lewis acid. As a Lewis acid, it possesses the ability to donate electrons to other molecules, enabling the catalysis of reactions between organic compounds and facilitating the electrochemical reduction of organic compounds. Furthermore, the complex has exhibited significant efficacy as a catalyst for carbon dioxide reduction. Rhodium(II) heptafluorobutyrate dimer stands as a valuable and versatile tool in scientific research, empowering advancements across various disciplines.


Rhodium(II) heptafluorobutyrate dimer (CAS 73755-28-9) References

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  3. Axial coordination of NHC ligands on dirhodium(II) complexes: generation of a new family of catalysts.  |  Trindade, AF., et al. 2008. J Org Chem. 73: 4076-86. PMID: 18457453
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  5. Metal-catalysed 1,2-diamination reactions.  |  Cardona, F. and Goti, A. 2009. Nat Chem. 1: 269-75. PMID: 21378869
  6. α-Amidino Rhodium Carbenes: Key Intermediates for the Preparation of (E)-2-Aminomethylene-3-oxoindoles and Pyranoindoles.  |  Qian, J., et al. 2016. Org Lett. 18: 3682-5. PMID: 27391393
  7. A Novel Electrophilic Diamination Reaction of Alkenes.  |  Li, G., et al. 2001. Angew Chem Int Ed Engl. 40: 4277-4280. PMID: 29712117

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Rhodium(II) heptafluorobutyrate dimer, 250 mg

sc-253431
250 mg
$143.00