Date published: 2025-12-9

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Iron(III) hexacyanoferrate(II) (CAS 14038-43-8)

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Alternate Names:
Prussian Blue; Iron(III) ferrocyanide
Application:
Iron(III) hexacyanoferrate(II) is an Iron Oxide dye
CAS Number:
14038-43-8
Molecular Weight:
859.25
Molecular Formula:
Fe4[Fe(CN)6]3
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Iron(III) hexacyanoferrate(II), also known as Prussian blue, is a compound with a distinctive blue color, used in research applications that involve the study of its electrochemical properties. Its structure, consisting of a mixed-valence iron-cyanide framework, allows it to undergo redox reactions, which are of particular interest in the development of electrochemical sensors and energy storage devices such as batteries and supercapacitors. The compound′s ability to exchange cations makes it useful for studies on ion-selective electrodes and in the removal of certain heavy metal ions from solutions, without focusing on clinical detoxification applications. In materials science, research on Iron(III) hexacyanoferrate(II) includes the investigation of its photophysical properties and its potential use as a pigment in art conservation and the engineering of coatings. Moreover, the compound′s porous lattice structure is of interest for the encapsulation of smaller molecules, which can be relevant for the design of novel material systems with specific functionalities.


Iron(III) hexacyanoferrate(II) (CAS 14038-43-8) References

  1. Charge-transfer band shifts in iron(III) hexacyanoferrate(II) by electro-intercalated cations via ground state-energy/lattice-energy link.  |  Rosseinsky, DR., et al. 2002. Chem Commun (Camb). 2988-9. PMID: 12536780
  2. Elution and decomposition of cyanide in soil contaminated with various cyanocompounds.  |  Matsumura, M. and Kojima, T. 2003. J Hazard Mater. 97: 99-110. PMID: 12573832
  3. Optical charge-transfer in iron(III)hexacyanoferrate(II): electro-intercalated cations induce lattice-energy-dependent ground-state energies.  |  Rosseinsky, DR., et al. 2003. Inorg Chem. 42: 6015-23. PMID: 12971772
  4. Thermodynamic clarification of the curious ferric/potassium ion exchange accompanying the electrochromic redox reactions of prussian blue, iron(III) hexacyanoferrate(II).  |  Rosseinsky, DR., et al. 2004. J Am Chem Soc. 126: 10472-7. PMID: 15315463
  5. Selective capture of cesium and thallium from natural waters and simulated wastes with copper ferrocyanide functionalized mesoporous silica.  |  Sangvanich, T., et al. 2010. J Hazard Mater. 182: 225-31. PMID: 20594644
  6. Chitin-Prussian blue sponges for Cs(I) recovery: from synthesis to application in the treatment of accidental dumping of metal-bearing solutions.  |  Vincent, C., et al. 2015. J Hazard Mater. 287: 171-9. PMID: 25646900

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Iron(III) hexacyanoferrate(II), 25 g

sc-269261
25 g
$50.00