Dichlorotriphenylphosphorane (CAS 2526-64-9)
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Dichlorotriphenylphosphorane is a chemical compound that functions as a powerful reagent in organic synthesis. Its mode of action involves the conversion of aldehydes and ketones to alkenes through the Wittig reaction. This process occurs through the formation of a phosphonium ylide intermediate, which subsequently undergoes a concerted [2+2] cycloaddition with the carbonyl compound, leading to the formation of the desired alkene product. The reactivity of dichlorotriphenylphosphorane allows for the selective and efficient synthesis of a wide range of alkenes, making it useful in the development of complex organic molecules. Dichlorotriphenylphosphorane′s ability to facilitate the stereoselective synthesis of alkenes further enhances its utility in organic chemistry.
Dichlorotriphenylphosphorane (CAS 2526-64-9) References
- (31)P solid state NMR study of structure and chemical stability of dichlorotriphenylphosphorane. | Gonnella, NC., et al. 2009. Magn Reson Chem. 47: 461-4. PMID: 19266488
- An ylide-like phosphasilene and striking formation of a 4π-electron, resonance-stabilized 2,4-disila-1,3-diphosphacyclobutadiene. | Inoue, S., et al. 2011. J Am Chem Soc. 133: 2868-71. PMID: 21322569
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Dichlorotriphenylphosphorane, 25 g | sc-234606 | 25 g | $40.00 | |||
Dichlorotriphenylphosphorane, 100 g | sc-234606A | 100 g | $129.00 |