Molecular structure of (Isopropenyloxy)trimethylsilane, CAS Number: 1833-53-0
(Isopropenyloxy)trimethylsilane (CAS 1833-53-0)
Alternate Names:
2-(Trimethylsiloxy)propene; Acetone enol trimethylsilyl ether; IPOTMS
Application:
(Isopropenyloxy)trimethylsilane is an enol silyl ether
CAS Number:
1833-53-0
Molecular Weight:
130.26
Molecular Formula:
C6H14OSi
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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SDS & Certificate of Analysis
(Isopropenyloxy)trimethylsilane is a chemical compound that functions as a silylating agent. Its mechanism of action involves the transfer of the isopropenyl group to a target molecule, leading to the formation of silyl enol ethers. This process occurs through a nucleophilic attack on the silicon atom by the oxygen atom of the target molecule, resulting in the formation of a covalent bond. (Isopropenyloxy)Trimethylsilane reaction is organic synthesis to protect carbonyl groups and facilitate subsequent transformations. (Isopropenyloxy)trimethylsilane can also participate in the synthesis of various organic compounds by serving as a precursor for the introduction of the isopropenyl group into target molecules.
(Isopropenyloxy)trimethylsilane (CAS 1833-53-0) References
- Carbon-sulfur bond formation between a ruthenium-coordinated thiyl radical and methyl ketones. | Poturovic, S., et al. 2005. Angew Chem Int Ed Engl. 44: 1883-7. PMID: 15712304
- First example of highly stereoselective synthesis of 1,2,3-trisubstituted cyclopropanes via chiral selenonium ylides. | Wang, HY., et al. 2009. Chemistry. 15: 3784-9. PMID: 19229932
- Total synthesis of (+/-)-powelline and (+/-)-buphanidrine. | Bogle, KM., et al. 2010. Org Lett. 12: 1252-4. PMID: 20175516
- Reinventing the De Mayo reaction: synthesis of 1,5-diketones or 1,5-ketoesters via visible light [2+2] cycloaddition of β-diketones or β-ketoesters with styrenes. | Martinez-Haya, R., et al. 2018. Chem Commun (Camb). 54: 11602-11605. PMID: 30264086
- A general 11C-labeling approach enabled by fluoride-mediated desilylation of organosilanes. | Qu, W., et al. 2020. Nat Commun. 11: 1736. PMID: 32269227
- Catalytic Asymmetric Additions of Enol Silanes to In Situ Generated Cyclic, Aliphatic N-Acyliminium Ions. | Grossmann, O., et al. 2022. Angew Chem Int Ed Engl. 61: e202115036. PMID: 34897932
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
(Isopropenyloxy)trimethylsilane, 1 g | sc-235415 | 1 g | $75.00 |