Molecular structure of Trimethyl(phenylthio)silane, CAS Number: 4551-15-9
Trimethyl(phenylthio)silane (CAS 4551-15-9)
CAS Number:
4551-15-9
Molecular Weight:
182.36
Molecular Formula:
C9H14SSi
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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Trimethyl(phenylthio)silane, also known as TMS, is widely used in many scientific and industrial applications due to its unique properties. It is an excellent solvent for a variety of organic compounds and is highly reactive. It is also used as a scavenger in chromatography to remove impurities from samples. Additionally, Trimethyl(phenylthio)silane is employed in mass spectrometry to identify unknown compounds and as a solvent in the synthesis of peptides and proteins.
Trimethyl(phenylthio)silane (CAS 4551-15-9) References
- Synthesis of oligosaccharides containing the X-antigenic trisaccharide (alpha-L-Fucp-(1----3)-[beta-D-Galp-(1----4)]-beta-D-GlcpNAc) at their nonreducing ends. | Jain, RK. and Matta, KL. 1992. Carbohydr Res. 226: 91-100. PMID: 1499025
- An efficient synthesis of L-idose and L-iduronic acid thioglycosides and their use for the synthesis of heparin oligosaccharides. | Tatai, J., et al. 2008. Carbohydr Res. 343: 596-606. PMID: 18237719
- Synthesis of a wide range of thioethers by indium triiodide catalyzed direct coupling between alkyl acetates and thiosilanes. | Nishimoto, Y., et al. 2012. Org Lett. 14: 1846-9. PMID: 22428542
- Propargylic sulfides: synthesis, properties, and application. | Vizer, SA., et al. 2015. Chem Rev. 115: 1475-502. PMID: 25517232
- Palladium-catalyzed coupling of azoles or thiazoles with aryl thioethers via C-H/C-S activation. | Zhu, F. and Wang, ZX. 2015. Org Lett. 17: 1601-4. PMID: 25719516
- Synthesis of Thioethers by InI₃-Catalyzed Substitution of Siloxy Group Using Thiosilanes. | Nishimoto, Y., et al. 2016. Molecules. 21: PMID: 27782065
- Transformation of Methylene Acetals to Bromoformates with a Combination of Trimethyl(phenylthio)silane and N-Bromosuccinimide. | Maegawa, T., et al. 2017. J Org Chem. 82: 7608-7613. PMID: 28640621
- Stereoselectivity in Glycosylation with Deoxofluorinated Glucosazide and Galactosazide Thiodonors. | Kurfiřt, M., et al. 2019. J Org Chem. 84: 6405-6431. PMID: 31062975
- A general 11C-labeling approach enabled by fluoride-mediated desilylation of organosilanes. | Qu, W., et al. 2020. Nat Commun. 11: 1736. PMID: 32269227
- Spirocyclic Nitroxides as Versatile Tools in Modern Natural Sciences: From Synthesis to Applications. Part I. Old and New Synthetic Approaches to Spirocyclic Nitroxyl Radicals. | Zaytseva, EV. and Mazhukin, DG. 2021. Molecules. 26: PMID: 33525514
- Chemoenzymatic synthesis of fluorinated polyketides. | Rittner, A., et al. 2022. Nat Chem. 14: 1000-1006. PMID: 35879443
- Chemical synthesis of a hexasaccharide comprising the Lewisx determinant linked beta-(1-->6) to a linear trimannosyl core and the precursor pentasaccharide lacking fucose. | Jain, RK. and Matta, KL. 1996. Carbohydr Res. 282: 101-11. PMID: 8721739
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Trimethyl(phenylthio)silane, 5 g | sc-258306 | 5 g | $107.00 |