Date published: 2026-5-14

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Phosphorus triiodide (CAS 13455-01-1)

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Alternate Names:
Phosphorus(III) iodide
CAS Number:
13455-01-1
Purity:
≥90%
Molecular Weight:
411.69
Molecular Formula:
PI3
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Phosphorus triiodide (PI3) is an extensively employed chemical compound within scientific research. It manifests as a yellowish-red solid, known for its high reactivity and potential hazards if mishandled. Phosphorus triiodide finds diverse applications encompassing organic synthesis, catalysis, and materials science. Within scientific research, phosphorus triiodide serves as a reagent for organic synthesis. Notably, it facilitates the conversion of alcohols into alkyl iodides, pivotal intermediates in the synthesis of pharmaceuticals and various organic compounds. Moreover, phosphorus triiodide assumes the role of a catalyst in numerous reactions, including the synthesis of carboxylic acids and esters. Its contributions extend to materials science, where it enables the synthesis of novel compounds characterized by unique properties. Phosphorus triiodide′s high reactivity endows it with the capacity to react with diverse organic compounds. As a potent oxidizing agent, it can cleave carbon-carbon bonds and transform alcohols into alkyl iodides. Furthermore, phosphorus triiodide can engage in reactions with water, resulting in the formation of phosphorous acid and hydroiodic acid. These distinct properties contribute to the compound′s versatility and significance within the realm of scientific research.


Phosphorus triiodide (CAS 13455-01-1) References

  1. CHROMATOGRAPHIC STUDIES ON THE HYDROLYSIS OF PHOSPHORUS COMPOUNDS. VII. THE HYDROLYSIS OF PHOSPHORUS TRIHALIDES AND PSEUDOHALIDES.  |  POLLARD, FH., et al. 1963. J Chromatogr. 11: 383-8. PMID: 14045497
  2. Phosphorus(I) iodide: a versatile metathesis reagent for the synthesis of low oxidation state phosphorus compounds.  |  Ellis, BD. and Macdonald, CL. 2006. Inorg Chem. 45: 6864-74. PMID: 16903744

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Phosphorus triiodide, 10 g

sc-236390
10 g
$89.00