Molecular structure of Palladium(II) acetate, CAS Number: 3375-31-3
Palladium(II) acetate (CAS 3375-31-3)
Alternate Names:
Palladium diacetate; Diacetoxypalladium
Application:
Palladium(II) acetate is a catalyst for intramolecular coupling
CAS Number:
3375-31-3
Molecular Weight:
224.51
Molecular Formula:
C4H6O4Pd
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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Palladium(II) acetate is a catalyst for an intramolecular coupling of aryl bromides with alcohols, resulting in the formation of 1,3-oxazepines. Additionally, it finds utility in the synthesis of cyclic ureas through palladium-catalyzed intramolecular cyclization. Palladium acetate monomer (Pd(OAc)2) serves as an oxidation catalyst in organic synthesis. Notably, it exhibits remarkable efficiency in converting trifluoroacetic acid into cyclohexene oxide, displaying high selectivity. Moreover, palladium acetate monomer forms stable complexes with nitrogen-containing compounds such as ammonia and amines. To enhance the stability of these complexes, sodium carbonate or plasma mass spectrometry can be employed.
Palladium(II) acetate (CAS 3375-31-3) References
- Palladium(II) Acetate-Tris(triphenylphosphine)rhodium(I) Chloride: A Novel Catalytic Couple for the Intramolecular Heck Reaction. | Bankston, D., et al. 1999. J Org Chem. 64: 3461-3466. PMID: 11674466
- Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media. | Ley, SV., et al. 2002. Chem Commun (Camb). 1134-5. PMID: 12122701
- Organometallic chemistry of azuliporphyrins: synthesis, spectroscopy, electrochemistry, and structural characterization of nickel(II), palladium(II), and platinum(II) complexes of azuliporphyrins. | Lash, TD., et al. 2003. Inorg Chem. 42: 7326-38. PMID: 14577805
- Non-trivial behavior of palladium(II) acetate. | Bakhmutov, VI., et al. 2005. Dalton Trans. 1989-92. PMID: 15909048
- 2-Tosyl-2,3,3a,4,9,9a-hexa-hydro-1H-benzo[f]isoindol-1-one. | Wu, M. and Hu, YM. 2013. Acta Crystallogr Sect E Struct Rep Online. 69: o926. PMID: 23795094
- Facile hydrolysis and alcoholysis of palladium acetate. | Bedford, RB., et al. 2015. Angew Chem Int Ed Engl. 54: 6591-4. PMID: 25865439
- Palladium(II)-Catalyzed Directed anti-Hydrochlorination of Unactivated Alkynes with HCl. | Derosa, J., et al. 2017. J Am Chem Soc. 139: 5183-5193. PMID: 28266849
- Directed C-H Bond Oxidation of Bridged Cycloalkanes Catalyzed by Palladium(II) Acetate. | Larrosa, M., et al. 2018. Chemistry. 24: 6269-6276. PMID: 29488690
- Palladium Acetate Revisited: Unusual Ring-Current Effects, One-Electron Reduction, and Metal-Metal Bonding. | Pakula, RJ., et al. 2018. Inorg Chem. 57: 8046-8049. PMID: 29969243
- Naphtho[2,3- b]carbaporphyrins. | Grabowski, EY., et al. 2018. J Org Chem. 83: 11825-11838. PMID: 30168327
- From Pincer to Paddlewheel: C-H and C-S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II). | Halder, P., et al. 2019. Inorg Chem. 58: 2270-2274. PMID: 30698431
- Synthesis, Characterization, and Non-Covalent Interactions of Palladium(II)-Amino Acid Complexes. | Hobart, DB., et al. 2021. Molecules. 26: PMID: 34299606
- Ligand Rearrangement Leads to Tetrahydrothiophene-Functionalized N,S-Heterocyclic Carbene Palladium(II) Complexes. | Romine, AM., et al. 2021. Organometallics. 40: 2311-2319. PMID: 34433997
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Palladium(II) acetate, 1 g | sc-253231 | 1 g | $141.00 | |||
Palladium(II) acetate, 5 g | sc-253231A | 5 g | $500.00 |