Molecular structure of Dicyclohexano-24-crown-8, CAS Number: 17455-23-1
Dicyclohexano-24-crown-8 (CAS 17455-23-1)
CAS Number:
17455-23-1
Molecular Weight:
460.60
Molecular Formula:
C24H44O8
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This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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Dicyclohexano-24-crown-8 is an organic compound that is extensively studied in the field of supramolecular chemistry. It is known for its ability to act as a host molecule in the formation of host-guest complexes with various cations, which is fundamental in understanding molecular recognition processes. In analytical chemistry, this compound is utilized in the selective extraction and transport of metal ions, which is valuable in the separation processes and the purification of elements. Its role in the stabilization of metal cations is also examined in the synthesis of new materials with specific ionic conductivities. Additionally, dicyclohexano-24-crown-8 is involved in research focused on the development of molecular machines and sensors, where its binding properties can be harnessed to create responsive systems. The compound is further used as a model to study the dynamics and thermodynamics of complexation in solution.
Dicyclohexano-24-crown-8 (CAS 17455-23-1) References
- Vertical ionisation potentials of a number of crown ethers from charge transfer bands of their EDA complexes. | Bhattacharya, S., et al. 2002. Spectrochim Acta A Mol Biomol Spectrosc. 58: 2841-8. PMID: 12477028
- Formation, dynamic behavior, and chemical transformation of Pt complexes with a rotaxane-like structure. | Suzaki, Y. and Osakada, K. 2006. Chem Asian J. 1: 331-43. PMID: 17441068
- Extraction-spectrophotometric determination of phenytoin in capsules and plasma using potassium permanganate/dicyclohexano-24-crown-8. | Korany, MA., et al. 1998. Talanta. 46: 9-14. PMID: 18967122
- Solvent extraction of barium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of slovafol 909. | Makrlík, E., et al. 2010. Acta Chim Slov. 57: 922-6. PMID: 24061897
- Thirteen cationic ionophores: their acute toxicity, neurobehavioral and membrane effects. | Gad, SC., et al. 1985. Drug Chem Toxicol. 8: 451-68. PMID: 4092618
- Rates of dediazoniations of arenediazonium ions complexed with 18-, 21- and 24-membered crown ethers | Hiroyuki Nakazumi, Ivanka Szele, Heinrich Zollinger ∗. 1981. Tetrahedron Letters. 22: 3053-3056.
- Spectrophotometry Determination of Calcium with Dicyclohexano-24-crown-8 and Propyl Orange by Solvent Extraction/Flow Injection Method | Shoji Motomizu, Mitsuko Oshima, Naomi Yoneda & Tadashi Iwachido. 1990. Analytical Sciences. 6: 215–220.
- Crown ethers as stationary phases in gas chromatography: Comparison between dibenzo-18-crown-6, dibenzo-24-crown-8 and dicyclohexano-24-crown-8 with respect to polarity, selectivity and stability | Nagaraj R. Ayyangar, Amruta S. Tambe, Sujata S. Biswas. 1991. Journal of Chromatography A. 543: 179-186.
- Macrocycle complexation chemistry. 37. The isolation and crystallographic characterization of the U4+ and UO2+ extraction complexes [(H5O2)(dicyclohexano-24-crown-8)]2[U02Cl4]⁗MeOH and [(H5O2) (dicyclohexano-24-crown-8)]2[UCl6]⁗MeOH | Robin D. Rogers & Matthew M. Benning. 1991. Journal of inclusion phenomena and molecular recognition in chemistry. 11: 121–135.
- Different Behavior of K- and Na- Interacting with K+ Complexed by Dicyclohexano-24-crown-8 in Tetrahydrofuran | Maria Sokol, Zbigniew Grobelny, and Andrzej Stolarzewicz. 1995. J. Phys. Chem. 99: 12670–12676.
- Influence of the kind of crown ether on the anionic polymerization of (phenoxymethyl)oxirane initiated by potassium tert-butoxide | . 1995. Macromolecular Chemistry and Physics. 196: 1301-1306.
- Spectrophotometric Study of Complexation of Dicyclohexano-24-crown-8 with [60]- and [70]Fullerenes and Other Acceptors | Avijit Saha, Sandip K. Nayak, Subrata Chottopadhyay, and Asok K. Mukherjee. 2003. J. Phys. Chem. B. 107: 11889–11892.
- PVC-based membranes of dicyclohexano-24-crown-8 as Cd(II) selective sensor | Vinod Kumar Gupta, Ajay Kumar Jain, Pankaj Kumar. 2006. Electrochimica Acta. 52: 736-741.
- Thermodynamic study for dicyclohexano-24-crown-8 complexes with K+, Rb+, Cs+ and Tl+ ions in binary acetonitrile–nitromethane mixtures by conductometric method | Mohammad Kazem Rofouei, Mehdi Taghdiri & Mojtaba Shamsipur. 2008. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 62: 231–237.
- 133Cs NMR Study of Cs+ Ion Complexes with Dibenzo-24-crown-8, Dicyclohexano-24-crown-8 and Dibenzo-30-crown-10 in Binary Acetonitrile-Nitromethane Mixtures | Mohammad Kazem Rofouei, Mehdi Taghdiri, Mojtaba Shamsipur & Kamal Alizadeh. 2010. Journal of Solution Chemistry. 39: 1350–1359.
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| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Dicyclohexano-24-crown-8, 1 g | sc-507092 | 1 g | $428.00 |