Date published: 2025-9-15

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B-Iodo-9-BBN (CAS 70145-42-5)

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Alternate Names:
9-Iodo-9-borabicyclo[3.3.1]nonane
CAS Number:
70145-42-5
Purity:
≥95%
Molecular Weight:
247.91
Molecular Formula:
C8H14BI
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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B-Iodo-9-BBN, also known as B-iodo-9-borabicyclo[3.3.1]nonane, is a boron-containing compound that features an iodine atom attached to the boron atom. β-Iodo-9-BBN, 1 M in hexanes, is an oxidation product derived from the ketone 9-BBN. It serves as a versatile synthetic reagent for oxidizing halides and enolate olefins. This compound facilitates the synthesis of aryl halides through its reaction with boron enolates, forming covalent bonds between the two components.


B-Iodo-9-BBN (CAS 70145-42-5) References

  1. A synthesis of aromatic five- and six-membered B-N heterocycles via ring closing metathesis.  |  Ashe, AJ. and Fang, X. 2000. Org Lett. 2: 2089-91. PMID: 10891237
  2. Inherently chiral resorcin[4]arenes: a new concept for improving the functionality.  |  Wiegmann, S. and Mattay, J. 2011. Org Lett. 13: 3226-8. PMID: 21591617
  3. Palladium(II)-Catalyzed Dehydroboration via Generation of Boron Enolates.  |  Sakamoto, Y., et al. 2016. Chemistry. 22: 18686-18689. PMID: 27734542
  4. Synthetic Strategy: Palladium-Catalyzed Dehydrogenation of Carbonyl Compounds.  |  Hirao, T. 2019. J Org Chem. 84: 1687-1692. PMID: 30668104
  5. Synthesis of Functionalized Cannabilactones.  |  Liu, Y., et al. 2020. Molecules. 25: PMID: 32041131

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

B-Iodo-9-BBN, 25 ml

sc-239266
25 ml
$196.00