Date published: 2025-9-28

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Ammonium iodide (CAS 12027-06-4)

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Application:
Ammonium iodide is an iodide salt used as a reagent and expectorant
CAS Number:
12027-06-4
Purity:
≥99%
Molecular Weight:
144.94
Molecular Formula:
NH4I
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Ammonium iodide, denoted by the chemical formula NH4I, is an inorganic compound that manifests as a white crystalline salt, highly soluble in water and hygroscopic in nature. This salt is formed by the reaction between ammonia and hydroiodic acid and is mainly used in the chemical and photographic industries. In the realm of chemical synthesis, ammonium iodide serves as a source of iodide ion, a reducing agent, and a nucleophile in various organic reactions. For instance, it is often used in the preparation of alkyl iodides from alcohols, where it acts by substituting a hydroxyl group with an iodide ion, a process facilitated by its iodide content. In research, ammonium iodide has been employed in studies focused on crystal growth and the properties of iodide-containing materials. Its ability to easily dissolve and subsequently release iodide ions makes it an ideal candidate for the synthesis and processing of iodide-based compounds in solid-state chemistry. Additionally, in the field of photovoltaics, ammonium iodide has been explored for its potential use in the fabrication of perovskite solar cells, where it contributes to the formation of the light-absorbing layer, crucial for the cell′s efficiency. This compound′s straightforward ionic nature and high solubility also make it a useful reagent in various laboratory protocols, aiding in the synthesis and analysis of complex chemical systems.


Ammonium iodide (CAS 12027-06-4) References

  1. Copper-mediated sequential cyanation of aryl C-B and arene C-H bonds using ammonium iodide and DMF.  |  Kim, J., et al. 2012. J Am Chem Soc. 134: 2528-31. PMID: 22280330
  2. [2-(Dimethyl-amino)-ethanol-κ(2)N,O][2-(dimethyl-amino)-ethano-lato-κ(2)N,O]iodidocopper(II).  |  Buvaylo, EA., et al. 2012. Acta Crystallogr Sect E Struct Rep Online. 68: m419-20. PMID: 22589798
  3. Copper-mediated selective cyanation of indoles and 2-phenylpyridines with ammonium iodide and DMF.  |  Kim, J., et al. 2012. Org Lett. 14: 3924-7. PMID: 22794272
  4. Copper-mediated transformation of organosilanes to nitriles with DMF and ammonium iodide.  |  Wang, Z. and Chang, S. 2013. Org Lett. 15: 1990-3. PMID: 23541176
  5. Asymmetric iodine catalysis-mediated enantioselective oxidative transformations.  |  Claraz, A. and Masson, G. 2018. Org Biomol Chem. 16: 5386-5402. PMID: 30024581
  6. Copper- and DMF-mediated switchable oxidative C-H cyanation and formylation of imidazo[1,2-a]pyridines using ammonium iodide.  |  Li, X., et al. 2020. Org Biomol Chem. 18: 9100-9108. PMID: 33150910
  7. Structure of a ternary complex of lactoperoxidase with iodide and hydrogen peroxide at 1.77 Å resolution.  |  Singh, PK., et al. 2021. J Inorg Biochem. 220: 111461. PMID: 33882424
  8. Preparation of Low Grain Boundary Perovskite Crystals with Excellent Performance: The Inhibition of Ammonium Iodide.  |  Gao, F., et al. 2021. ACS Omega. 6: 12858-12865. PMID: 34056437
  9. Manipulated Crystallization and Passivated Defects for Efficient Perovskite Solar Cells via Addition of Ammonium Iodide.  |  Qi, W., et al. 2021. ACS Appl Mater Interfaces. 13: 34053-34063. PMID: 34254770
  10. Exploring the Effect of Ammonium Iodide Salts Employed in Multication Perovskite Solar Cells with a Carbon Electrode.  |  Bidikoudi, M., et al. 2021. Molecules. 26: PMID: 34641280
  11. Structural evidence of the oxidation of iodide ion into hyper-reactive hypoiodite ion by mammalian heme lactoperoxidase.  |  Singh, PK., et al. 2022. Protein Sci. 31: 384-395. PMID: 34761444

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Ammonium iodide, 100 g

sc-202939
100 g
$120.00

Ammonium iodide, 500 g

sc-202939A
500 g
$460.00