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(Acetylacetonato)dicarbonylrhodium(I) (CAS 14874-82-9)

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Alternate Names:
Dicarbonyl-acetylacetonato-rhodium(I); Dicarbonylrhodium(I) 2,4-pentanedionate; Rhodium(I) dicarbonyl acetylacetonate
Application:
(Acetylacetonato)dicarbonylrhodium(I) is a catalyst for various carbonylation reactions
CAS Number:
14874-82-9
Molecular Weight:
258.03
Molecular Formula:
C7H7O4Rh
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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(Acetylacetonato)dicarbonylrhodium(I) is a compound of interest primarily in the field of organometallic chemistry and catalysis. It is frequently used as a catalyst or a catalyst precursor in a variety of chemical reactions, including hydroformylation, where it facilitates the addition of a formyl group to alkenes. In addition, it serves as a starting material for the synthesis of other rhodium complexes, which are explored for their catalytic properties in asymmetric synthesis, allowing the preparation of chiral molecules that are important in the synthesis of natural products and fine chemicals. Its role in homogeneous catalysis is also studied, with researchers investigating the mechanisms by which (Acetylacetonato)dicarbonylrhodium(I) activates substrates and transfers functional groups. Moreover, this compound is used in mechanistic studies to understand the fundamental steps involved in metal-mediated transformations, providing insights into reaction kinetics and the development of improved catalyst systems.


(Acetylacetonato)dicarbonylrhodium(I) (CAS 14874-82-9) References

  1. Exchanging conformations of a hydroformylation catalyst structurally characterized using two-dimensional vibrational spectroscopy.  |  Panman, MR., et al. 2013. Inorg Chem. 52: 14294-8. PMID: 24256078
  2. Distinguishing Population and Coherence Transfer Pathways in a Metal Dicarbonyl Complex Using Pulse-Shaped Two-Dimensional Infrared Spectroscopy.  |  Marroux, HJ. and Orr-Ewing, AJ. 2016. J Phys Chem B. 120: 4125-30. PMID: 27070852
  3. Rhodium(I) carbonyl complexes based on naphthophosphacyclophanes  |  , et al. (2017). Russian Chemical Bulletin. volume 66,: pages 924–926.
  4. Kinetics of the hydroformylation of soybean oil by ligand-modified homogeneous rhodium catalysis  |  , et al. (2002). Journal of the American Oil Chemists' Society. volume 79,: pages 1221–1225.
  5. Measurement of solubilities for rhodium complexes and phosphine ligands in supercritical carbon dioxide  |  Y Shimoyama, M Sonoda, K Miyazaki, H Higashi… - The Journal of …, 2008 - Elsevier. April 2008,. The Journal of Supercritical Fluids. Volume 44, Issue 3,: Pages 266-272.
  6. Density Functional Theory Study of Substitution at the Square-Planar Acetylacetonato-dicarbonyl-rhodium(I) Complex  |  Kathrin Helen Hopmann† and Jeanet Conradie*†‡. 2009. Organometallics., 28, 13,: 3710–3715.
  7. Rhodium-Catalyzed Addition of α-Keto Acid Chlorides with Terminal Alkynes  |  T Kashiwabara, M Tanaka - Advanced Synthesis & Catalysis, 2011 - Wiley Online Library. June 2011. Advanced Synthesis & Catalysis. Volume353, Issue9: Pages 1485-1490.
  8. Solute–solvent interactions: two-dimensional ultrafast infrared vibrational echo experiments  |  DE Thompson, KA Merchant, MD Fayer - Chemical physics letters, 2001 - Elsevier. 1 June 2001,. Chemical Physics Letters. Volume 340, Issues 3–4,: Pages 267-274.
  9. Coordination Chemistry of the PdmBOX Pincer Ligand: Reactivity at the Metal and the Ligand  |   and Jan Wenz, Vladislav Vasilenko, Alexander Kochan, Hubert Wadepohl, Lutz H. Gade. 03 November 2017. European Journal of Inorganic Chemistry. Volume2017, Issue47: Pages 5545-5556.
  10. Using ultrafast infrared multidimensional correlation spectroscopy to aid in vibrational spectral peak assignments  |  JB Asbury, T Steinel, MD Fayer - Chemical physics letters, 2003 - Elsevier. 4 November 2003,. Chemical Physics Letters. Volume 381,: Issues 1–2, Pages 139-146.
  11. T2 selective scanning vibrational echo spectroscopy  |  KD Rector, MD Fayer, JR Engholm, E Crosson… - Chemical physics …, 1999 - Elsevier. 14 May 1999,. Chemical Physics Letters. Volume 305, Issues 1–2,: Pages 51-56.
  12. Polymers based on exo-silicon-substituted norbornenes for membrane gas separation  |  MA Guseva, DA Alentiev, DS Bakhtin, IL Borisov… - Journal of Membrane …, 2021 - Elsevier. 15 November 2021,. Journal of Membrane Science. Volume 638,: 119656.
  13. Continuous liquid-phase hydroformylation of 1-hexene with a poly-TRIM bound rhodium-phosphine complex  |  C Andersson, A Nikitidis, J Hjortkj, B Heinrich - Applied Catalysis A …, 1993 - Elsevier. 26 March 1993,. Applied Catalysis A: General. Volume 96, Issue 2,: Pages 345-354.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

(Acetylacetonato)dicarbonylrhodium(I), 250 mg

sc-252349
250 mg
$243.00