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5-Phenyldipyrromethane (CAS 107798-98-1)

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Application:
5-Phenyldipyrromethane is a porphyrin building block
CAS Number:
107798-98-1
Molecular Weight:
222.29
Molecular Formula:
C15H14N2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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5-Phenyldipyrromethane functions as a building block in the synthesis of various organic molecules. Its mechanism of action involves participating in cross-coupling reactions to form carbon-carbon bonds. 5-Phenyldipyrromethane acts as a key intermediate in the preparation of porphyrin-based materials and other organic compounds, contributing to the development of novel materials and compounds for research purposes. Through its involvement in synthetic pathways, 5-Phenyldipyrromethane plays a role in the creation of diverse molecular architectures, enabling the exploration of new chemical properties and potential applications in various experimental applications.


5-Phenyldipyrromethane (CAS 107798-98-1) References

  1. Efficient synthesis of monoacyl dipyrromethanes and their use in the preparation of sterically unhindered trans-porphyrins.  |  Rao, PD., et al. 2000. J Org Chem. 65: 1084-92. PMID: 10814057
  2. Isoindoline nitroxide-labeled porphyrins as potential fluorescence-suppressed spin probes.  |  Liu, F., et al. 2017. Org Biomol Chem. 15: 1245-1253. PMID: 28098314
  3. 5, 10-Diphenyltripyrrane, a useful building block for the synthesis of meso-phenyl substituted expanded macrocycles  |  Brückner, C., Sternberg, E. D., Boyle, R. W., & Dolphin, D. 1997. Chemical Communications. (17): 1689-1890.
  4. Novel and improved syntheses of 5, 15‐diphenylporphyrin and its dipyrrolic precursors  |  Brückner, C., Posakony, J. J., Johnson, C. K., Boyle, R. W., James, B. R., & Dolphin, D. 1998. Journal of Porphyrins and Phthalocyanines. 2(6): 455-465.
  5. Selective synthesis of asymmetrically substituted 5, 15-diphenylporphyrins  |  Clarke, O. J., & Boyle, R. W. 1998. Tetrahedron letters. 39(39): 7167-7168.
  6. Investigation of porphyrin-forming reactions. Part 3. 1 The origin of scrambling in dipyrromethane+ aldehyde condensations yielding trans-A 2 B 2-tetraarylporphyrins  |  Geier III, G. R., Littler, B. J., & Lindsey, J. S. 2001. Journal of the Chemical Society, Perkin Transactions 2. (5): 701-711.
  7. A scalable synthesis of meso-substituted dipyrromethanes  |  Laha, J. K., Dhanalekshmi, S., Taniguchi, M., Ambroise, A., & Lindsey, J. S. 2003. Organic process research & development. 7(6): 799-812.
  8. Use of orthoesters in the synthesis of meso-substituted porphyrins  |  Fox, S., Hudson, R., & Boyle, R. W. 2003. Tetrahedron letters. 44(6): 1183-1185.
  9. Efficient synthesis of meso-substituted corroles in a H2O− MeOH mixture  |  Koszarna, B., & Gryko, D. T. 2006. The Journal of organic chemistry. 71(10): 3707-3717.
  10. Synthesis of meso-tetraarylporphyrins using SeO2 as oxidant  |  Ló, S. M., Ducatti, D. R., Duarte, M. E. R., Barreira, S. M., Noseda, M. D., & Gonçalves, A. G. 2011. Tetrahedron letters. 52(13): 1441-1443.
  11. Functionalization of dipyrromethanes via hetero-Diels–Alder reaction with azo-and nitrosoalkenes  |  Pereira, N. A., Lemos, A., Serra, A. C., & e Melo, T. M. P. 2013. Tetrahedron Letters. 54(12): 1553-1557.
  12. Synthesis and Properties of Isoindoline Nitroxide‐Containing Porphyrins  |  Liu, F., Shen, Y. C., Ouyang, Y. H., Yan, G. P., Chen, S., Liu, H.,.. & Wu, J. Y. 2017. Journal of Heterocyclic Chemistry. 54(6): 3143-3151.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

5-Phenyldipyrromethane, 500 mg

sc-262708
500 mg
$122.00

5-Phenyldipyrromethane, 1 g

sc-262708A
1 g
$192.00

5-Phenyldipyrromethane, 5 g

sc-262708B
5 g
$809.00

5-Phenyldipyrromethane, 500 g

sc-262708C
500 g
$30600.00