Molecular structure of 4,4′-Di-tert-butyl-2,2′-dipyridyl, CAS Number: 72914-19-3
4,4′-Di-tert-butyl-2,2′-dipyridyl (CAS 72914-19-3)
Alternate Names:
BBBPY
Application:
4,4′-Di-tert-butyl-2,2′-dipyridyl is a bipyridyl ligand for catalyst and material design
CAS Number:
72914-19-3
Purity:
≥99%
Molecular Weight:
268.40
Molecular Formula:
C18H24N2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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SDS & Certificate of Analysis
4,4′-Di-tert-butyl-2,2′-dipyridyl is a bipyridyl compound that is widely employed as a ligand for transition metals in the preparation of catalysts and functional materials. 4,4′-Di-tert-butyl-2,2′-dipyridyl has been utilized in the preparation of electron-transfer mediators for light-active materials, and in the preparation of stable Pd(IV) monoaryl fluoride complexes for the study of Pd-mediated aryl-fluoride bond formation. Other organometallic complexes or iridium and related metals have been prepared incorporating 4,4′-Di-tert-butyl-2,2′-dipyridyl for applications to small molecule and materials synthesis.
4,4′-Di-tert-butyl-2,2′-dipyridyl (CAS 72914-19-3) References
- Substituted polypyridine complexes of cobalt(II/III) as efficient electron-transfer mediators in dye-sensitized solar cells. | Sapp, SA., et al. 2002. J Am Chem Soc. 124: 11215-22. PMID: 12224970
- Efficient yellow electroluminescence from a single layer of a cyclometalated iridium complex. | Slinker, JD., et al. 2004. J Am Chem Soc. 126: 2763-7. PMID: 14995193
- A series of [3 + 2] cycloaddition products from the reaction of rhenium oxo complexes with diphenyl ketene. | Middleditch, M., et al. 2007. Inorg Chem. 46: 2797-804. PMID: 17338517
- Synthesis and reactivity of a mono-sigma-aryl palladium(IV) fluoride complex. | Ball, ND. and Sanford, MS. 2009. J Am Chem Soc. 131: 3796-7. PMID: 19249867
- Raman Spectra of Persistent Radical Anions from Benzophenone, Fluorenone, 2,2'-Bipyridyl, 4,4'-Di-tert-butyl-2,2'-dipyridyl, and Anthracene: Excellent Agreement between DFT and Experiment for Highly Delocalized Radical Systems. | Juneau, A. and Frenette, M. 2021. J Phys Chem B. 125: 1595-1603. PMID: 33544614
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
4,4′-Di-tert-butyl-2,2′-dipyridyl, 5 g | sc-254729 | 5 g | $87.00 |