Molecular structure of 1-Aza-12-crown-4, CAS Number: 41775-76-2
1-Aza-12-crown-4 (CAS 41775-76-2)
Alternate Names:
1-Aza-12-crown 4-Ether
CAS Number:
41775-76-2
Molecular Weight:
175.23
Molecular Formula:
C8H17NO3
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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SDS & Certificate of Analysis
1-Aza-12-crown-4 is a chemical compound that functions as a complexing agent in various experimental applications. It has the ability to selectively bind to metal ions, particularly alkali and alkaline earth metal ions, due to its crown ether structure. 1-Aza-12-crown-4 can form stable complexes with metal ions, altering their chemical and physical properties. In experimental applications, 1-Aza-12-crown-4 is used to sequester metal ions from a mixture, allowing for their isolation and analysis. Its mode of action involves the formation of coordination complexes with metal ions, leading to the enhancement of their solubility and reactivity. 1-Aza-12-crown-4′s ability to selectively bind to metal ions may be useful various research and development applications, particularly in the field of analytical chemistry.
1-Aza-12-crown-4 (CAS 41775-76-2) References
- Adsorption and isotope effects by ion exchange with 1-aza-12-crown-4 bonded Merrifield peptide resin. | Kim, DW., et al. 2003. J Colloid Interface Sci. 263: 528-32. PMID: 12909044
- Influence of aza crown ethers on the electric percolation of AOT/isooctane/water (w/o) microemulsions. | Dasilva-Carvalhal, J., et al. 2006. J Colloid Interface Sci. 301: 637-43. PMID: 16782122
- 7Li NMR chemical shift titration and theoretical DFT calculation studies: solvent and anion effects on second-order complexation of 12-crown-4 and 1-aza-12-crown-4 with lithium cation in several aprotic solvents. | Masiker, MC., et al. 2010. Magn Reson Chem. 48: 94-100. PMID: 19950215
- Functionalized mesoporous silicas with crown ether moieties for selective adsorption of lithium ions in artificial sea water. | Sung, SP., et al. 2014. J Nanosci Nanotechnol. 14: 8845-51. PMID: 25958615
- Magnetic interaction of photoexcited terbium-porphyrin complexes with non-aromatic ligands having different symmetries. | Adi, LC., et al. 2022. Dalton Trans. 51: 6186-6196. PMID: 35383819
- Lithium sensors based on photophysical changes of 1-aza-12-crown-4 naphthalene derivatives synthesized via Buchwald-Hartwig amination. | Kim, H. and Koo, B. 2022. RSC Adv. 12: 31976-31984. PMID: 36380950
- Thermodynamic, Structural, and Conductance Studies of Lithium Coronand Electrolytes Relevant to Lithium Battery Technology | Danil de Namor, A. F., Llosa Tanco, M. A., Salomon, M., & Ng, J. C. 1994. The Journal of Physical Chemistry. 98(45): 11796-11802.
- Interaction between Monoaza-, Diaza-, or Polyazacrown Ethers and Alkali Metal Ions in Acetonitrile by Polarography | Hojo, M., Hisatsune, I., Tsurui, H., & Minami, S. I. 2000. Analytical sciences. 16(12): 1277-1284.
- Fluorescent Chemosensors for Heavy Metal Ions Based on Bis(terpyridyl) Ruthenium(II) Complexes Containing Aza-Oxa and Polyaza Macrocycles | Padilla‐Tosta, M. E., Lloris, J. M., Martínez‐Máñez, R., Marcos, M. D., Miranda, M. A., Pardo, T.,.. & Soto, J. 2001. European Journal of Inorganic Chemistry. 2001(6): 1475-1482.
- Chromatographic separation of magnesium isotopes by monoazacrown bonded Merrifield peptide resins | Kim, D. 2002. Journal of radioanalytical and nuclear chemistry. 252(1): 129-132.
- 'meta-Wurster's crowns': The synthesis and properties of meta-Phenylenediamine-based macrocycles | Sibert, J. W., Seyer, D. J., & Hundt, G. R. 2002. Journal of Supramolecular Chemistry. 2(1-3): 335-342.
- Manganese sequestration and improved high-temperature cycling of Li-ion batteries by polymeric aza-15-crown-5 | Li, Z., Pauric, A. D., Goward, G. R., Fuller, T. J., Ziegelbauer, J. M., Balogh, M. P., & Halalay, I. C. 2014. Journal of Power Sources. 272: 1134-1141.
- The role of the size of aza-crown recognition moiety in azaphthalocyanine fluorescence sensors for alkali and alkaline earth metal cations | Lochman, L., Svec, J., Roh, J., & Novakova, V. 2015. Dyes and pigments. 121: 178-187.
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| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
1-Aza-12-crown-4, 1 g | sc-251478 | 1 g | $317.00 |