Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(hexafluorophosphate) complexA luminescent oxygen probe

Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(hexafluorophosphate) complex (CAS 123148-15-2)

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Synonym: Ru(dpp)3(PF6)2
Application: A luminescent oxygen probe
CAS Number: 123148-15-2
Purity: ≥98%
Molecular Weight: 1388.19
Molecular Formula: C72H48RuF12N6P2
* Refer to Certificate of Analysis for lot specific data (including water content).
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Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(hexafluorophosphate) complex is a preparation of ruthenium used in the design of chemiluminescent optical sensors for oxygen detection. Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(hexafluorophosphate) has also been described in the design and construction of solid-state light-emitting electrochemical cells.


References

1. Bolink, H.J., et al. 2006. J. Am. Chem. Soc. 128: 46-47. PMID: 16390114
2. Badocco, D., et al. 2008. Anal. Chim. Acta. 627: 239-246. PMID: 18809079
3. Kim, H.J., et al. 2008. Talanta. 76: 1070-1076. PMID: 18761157
4. Francis, P.S., et al. 2010. Talanta. 82: 859-862. PMID: 20602982

Physical State :
Solid
Solubility :
Soluble in DMF, Chloroform, Ethanol, and Methanol
Storage :
Desiccate at room temperature
Fluoresence :
λex 455 nm, λem 615 nm in 0.1 M phosphate pH 7.0
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
PubChem CID :
16218607
MDL Number :
MFCD03791108
SMILES :
C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2]

Download SDS (MSDS)

Certificate of Analysis

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I want to detect the oxygen from 35% w/w H2O2 solution. Does H2O2 also react with this dye? Second question, What is the composition of this production? Is it pure or mixed with other material (eg. polystyrene beads)? Thanks a lot for your answer

Asked by: Guoxiang
Thank you for your question. We do not know if this compound is reactive with H2O2. This chemical is a complex of tris(bathophenanthroline) ruthenium(II) and 2 hexafluorophosphate molecules. It is not mixed with any other compounds.
Answered by: Technical Support
Date published: 2017-10-10
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