Silver trifluoromethanesulfonate

Silver trifluoromethanesulfonate (CAS 2923-28-6)

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Synonym: Silver triflate; Trifluoromethanesulfonic acid silver salt
Application: CAS: 2923-28-6, MF: CF3SO3Ag, MW: 256.94, Purity: ≥98%
CAS Number: 2923-28-6
Purity: ≥98%
Molecular Weight: 256.94
Molecular Formula: CF3SO3Ag
* Refer to Certificate of Analysis for lot specific data (including water content).
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Yields olefins from secondary phosphates and thiophosphates. Using this reagent the etherification of alcohols with primary alkyl halides can be accomplished under mild conditions. Used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. Additionally, employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.


References

1. Tetrahedron Lett. 36, 719, (1995) 2. Tetrahedron Lett. 35, 8111, (1994) 3. J. Org. Chem. 71, 9248, (2006) 4. Chem. Commun. , 1359, (2006)

Appearance :
Powder
Physical State :
Solid
Solubility :
Soluble in water.
Storage :
Store at 4° C
Melting Point :
286° C (lit.)
Density :
~1.88 g/cm3 (Predicted)
Refractive Index :
n20D ~1.35 (Predicted)
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
WGK Germany :
3
PubChem CID :
76223
MDL Number :
MFCD00013226
EC Number :
220-882-2
Beilstein Registry :
3598402
SMILES :
C(F)(F)(F)S(=O)(=O)[O-].[Ag+]

Download SDS (MSDS)

Certificate of Analysis

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