(R)-(+)-(6,6prime-Dimethoxybiphenyl-2,2prime-diyl)bis(diphenylphosphine) CAS: 133545-16-1
MF: C38H32O2P2
MW: 582.61
A synthesis regeant.

(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) (CAS 133545-16-1)

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Alternate Names: (R)-(+)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; (R)-(+)-MeO-BIPHEP
CAS Number: 133545-16-1
Purity: ≥97%
Molecular Weight: 582.61
Molecular Formula: C38H32O2P2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data (including water content).
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(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) is a synthesis regeant used in the hydrogenation of α- and β-functionalized ketones, hydrogenation of heteroarenes, and C–C coupling reactions.


References

1. R. Schmid et al. Helv. Chim. Acta 74, 370, (1991) 2. R. Schmid et al. Pure Appl. Chem. 68, 131-138, (1996) 3. B. Heiser et al. Tet. Asym. 2, 51, (1991) 4. V. Blandin et al. Eur. J. Org. Chem., 1787, (1999) 5. J.R. Labrosse et al. Tet. Asym. 10, 1069, (1999)

Physical State :
Solid
Storage :
Store at room temperature
Melting Point :
213-216° C
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
PubChem CID :
SMILES :
COC1=C(C(=CC=C1)P(C2=CC=CC=C2)C3=CC=CC=C3)C4=C(C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)OC

Download SDS (MSDS)

Certificate of Analysis

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