Copper(I) trifluoromethanesulfonate benzene complex has catalyzed allylic oxidation of cyclic alkenes enantioselectively. In combination with amino acid-based chiral phosphine ligands, catalyzes asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity.
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