Copper(I) trifluoromethanesulfonate benzene complex

Copper(I) trifluoromethanesulfonate benzene complex (CAS 42152-46-5)

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Application: Catalyzes asymmetric conjugate additions
CAS Number: 42152-46-5
Purity: ≥90%
Molecular Weight: 503.34
Molecular Formula: (CF3SO3Cu)2•C6H6
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Copper(I) trifluoromethanesulfonate benzene complex has catalyzed allylic oxidation of cyclic alkenes enantioselectively. In combination with amino acid-based chiral phosphine ligands, catalyzes asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity.


References

1. J. Am. Chem. Soc. 126, 96, (2004) 2. J. Org. Chem. 69, 3121, (2004)

Appearance :
Powder
Physical State :
Solid
Storage :
Store at 4° C
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
Transport :
UN 3175, Class 4.1, Packing group II
PubChem CID :
10907261
SMILES :
C1=CC=CC=C1.C(F)(F)(F)S(=O)(=O)O.C(F)(F)(F)S(=O)(=O)O.[Cu].[Cu]

Download SDS (MSDS)

Certificate of Analysis

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