Tetrabutylammonium Perrhenate (CAS 16385-59-4)
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Tetrabutylammonium perrhenate, referred to as TBA-Pr, is an organic compound that finds wide-ranging applications in scientific research. It is a salt composed of tetrabutylammonium cation and perrhenate anion. In laboratory experiments, Tetrabutylammonium Perrhenate is extensively utilized to investigate the properties of organic compounds and explore chemical reactions. Moreover, Tetrabutylammonium Perrhenate is instrumental in the synthesis of diverse organic compounds. Additionally, it finds utility in electrochemical studies, serves as a reagent for the determination of metal ions, and acts as a catalyst in various organic reactions. Tetrabutylammonium perrhenate exhibits several mechanisms of action. It functions as an oxidizing agent, facilitating the oxidation of organic compounds and generating a diverse array of products. Furthermore, it can serve as a reducing agent, enabling the reduction of metal ions and the formation of metal complexes. It also acts as a proton donor, contributing protons to organic compounds and leading to the formation of novel products. Lastly, it serves as a catalyst, promoting the reaction of organic compounds.
Tetrabutylammonium Perrhenate (CAS 16385-59-4) References
- Ion pairing as a strategy for extraction by modified supercritical carbon dioxide: extraction of radioactive metal ions. | Gawenis, JA., et al. 2001. Anal Chem. 73: 2022-6. PMID: 11354485
- Discrete and monodimensional heteropolynuclear structures formed by tetracarboxylatodiruthenium(II,III) and perrhenato fragments. | Arribas, G., et al. 2005. Inorg Chem. 44: 5770-7. PMID: 16060629
- Anion-π Interaction Powered Perrhenate Recognition and Extraction in Aqueous Media. | Qin, H., et al. 2023. Inorg Chem. 62: 6458-6466. PMID: 37043341
- Comparison of the chemical and biological properties of trans-[Tc(DMPE)2Cl2]+ and trans-[Re(DMPE)2Cl2]+, where DMPE = 1,2-bis(dimethylphosphino)ethane. Single-crystal structural analysis of trans-[Re(DMPE)2Cl2]PF6 | Jean Luc Vanderheyden, Mary Jane Heeg, and Edward Deutsch. 1985. norg. Chem., 24, 11,: 1666–1673.
- Rearrangement of Allylic and Propargylic Alcohols Catalyzed by the Combined Use of tetrabutylammonium perrhenate (VII) and p-toluenesulfonic acid | K Narasaka, H Kusama, Y Hayashi - Tetrahedron, 1992 - Elsevier. 1992,. Tetrahedron. Volume 48, Issue 11,: Pages 2059-2068.
- Beckmann Rearrangement Catalyzed by the Combined Use of Tetrabutylammonium Perrhenate(VII) and Trifluoromethanesulfonic Acid | Narasaka Koichi 1, Kusama Hiroyuki 1, Yamashita Yuko 1, Sato Hiroshi 2. 1993,. Chemistry Letters. Vol.22, No.3: 489-492.
- Rapid Ion Exchange during Redox Switching of Poly(3-methylthiophene) Studied by X-ray Photoelectron Spectroscopy | Cynthia M. G. Bach and John R. Reynolds. 1994,. Phys. Chem. 98, 51,: 13636–13642.
- Synthesis of Quinolines via Intramolecular Cyclization of Benzylacetone Oxime Derivatives Catalyzed with Tetrabutylammonium Perrhenate(VII) and Trifluoromethanesulfonic Acid | Kusama Hiroyuki 1, Yamashita Yuko 1, Narasaka Koichi 1. 1995,. Chemistry Letters. Vol.24, No.1: 5-6.
- Synthesis of Azaspirodienones via Intramolecular Cyclization of p-Hydroxybenzylacetone Oximes and Their Transformation into Quinolines | Kusama Hiroyuki 1, Uchiyama Katsuya 1, Yamashita Yuko 1, Narasaka Koichi 1. 1995,. Chemistry Letters. Vol.24, No.8: 715-716.
- Carotenoids and related polyenes. Part 3. First total synthesis of fucoxanthin and halocynthiaxanthin using oxo-metallic catalyst | Yumiko Yamano, Chisato Tode and Masayoshi Ito. 1995,. Journal of the Chemical Society, Perkin Transactions 1. 1: 1895-1904.
- Transformation of Oximes of Phenethyl Ketone Derivatives to Quinolines and Azaspirotrienones Catalyzed by Tetrabutylammonium Perrhenate and Trifluoromethanesulfonic Acid | Kusama Hiroyuki 1, Yamashita Yuko 1, Uchiyama Katsuya 1, Narasaka Koichi 1. 1997,. BCSJ Award Article. Vol.70, No.5: 965-975.
- Highly efficient Beckmann rearrangement and dehydration of oximes | D Li, F Shi, S Guo, Y Deng - Tetrahedron Letters, 2005 - Elsevier. 24 January 2005,. Tetrahedron Letters. Volume 46, Issue 4,: Pages 671-674.
- Formation of ε-caprolactam via catalytic Beckmann rearrangement using P2O5 in ionic liquids | RX Ren, LD Zueva, W Ou - Tetrahedron Letters, 2001 - Elsevier. 26 November 2001,. Tetrahedron Letters. Volume 42, Issue 48,: Pages 8441-8443.
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Tetrabutylammonium Perrhenate, 1 g | sc-296489 | 1 g | $158.00 | |||
Tetrabutylammonium Perrhenate, 5 g | sc-296489A | 5 g | $474.00 |